一.命名下列各化合物或写出结构式(每题1分,共10分)1.(H3C)2HCCCC(CH3)3HH2.3-乙基-6-溴-2-己烯-1-醇3.OCH34.CHO5.邻羟基苯甲醛6.苯乙酰胺7.OH8.对氨基苯磺酸9.COOH10.甲基叔丁基醚二.试填入主要原料,试剂或产物(必要时,指出立体结构),完成下列各反应式。(每空2分,共48分)1.CHCHBrKCN/EtOHCH2Cl2.1+C12高温、高压①②O3H2OZn粉3.CH=CH2CHHBrMg3COCH3①+醚H2OH②CH3COC14.+CO2CH35.1,B2H6-2,H2O2,OH1,Hg(OAc)2,H2O-THF2,NaBH46.OOOOO7.CH2ClNaOHH2OCl8.CH3-+H2OOHClSN1历程+9.OOCH3C2H5ONaC2H5ONa+CH2=CHCCH3OBrZnEtOHBr10.211.OC+CH3+Cl2H12.CH3(2)HNO3H2SO4Fe,HCl(CH3CO)2OBr2NaOHNaNO2H3PO2H2SO4三.选择题。(每题2分,共14分)1.与NaOH水溶液的反应活性最强的是()(A).CH3CH2COCH2Br(B).CH3CH2CHCH2Br(C).(CH3)3CH2Br(D).CH3(CH2)2CH2BrCH32.对CH3Br进行亲核取代时,以下离子亲核性最强的是:()(A).CH3COO-(B).CH3CH2O-(C).C6H5O-(D).OH-3.下列化合物中酸性最强的是()(A)CH3CCH(B)H2O(C)CH3CH2OH(D)p-O2NC6H4OH(E)C6H5OH(F)p-CH3C6H4OH4.下列化合物具有旋光活性得是:()COOHOHHCH3A,B,HOHCH3COOHC,(2R,3S,4S)-2,4-二氯-3-戊醇5.下列化合物不发生碘仿反应的是()A、C6H5COC3HB、C2H5OHC、CH3CH2COC2HCH3D、CH3COC2HCH36.与HNO2作用没有N2生成的是()A、H2NCON2HB、CH3CH(NH2)COOHC、C6H5NHCH3D、C6H5NH27.能与托伦试剂反应产生银镜的是()3A、CCl3COOHB、CH3COOHC、CH2ClCOOHD、HCOOH参考答案一.命名下列各化合物或写出结构式(每题1分,共10分)1.(Z)-或顺-2,2,5-三甲基-3-己烯2.CH2CH2HOCH2CHCCH2CH2CH2Br3.(S)-环氧丙烷4.3,3-二甲基环己基甲醛NH2OHO5.CHO6.2-phenylacetamide7.α-萘酚HO3SNH28.9.4-环丙基苯甲酸O10.二.试填入主要原料,试剂或产物(必要时,指出立体结构),完成下列各反应式。(每空2分,共48分)1.2.C1BrC1OHCCHCH2CH2CH2CHO;CN34.5.6.OH(上面)OHNH2NH2,NaOH,CO2CH3(下面)(HOCH2CH2)2O7.8.CH2OHCH3OHCH3+ClOH49.10.OCH3CH2OCH3CH2OCCH3OO11.OCCH2Cl12.CH3CH3CH3CH3CH3(2)HNO3H2SO4Fe,HCl(CH3CO)2OBr2BrCH3NO2NH2NHCOCH3NHCOCH3CH3NaOHNaNO2H3PO2NH2BrH2SO4Br三.选择题。(每题2分,共14分)1.A2.B3.D4.A5.C6.C7.D四.鉴别(6分,分步给分)六.推断结构。(每2分,共8分)OA.CH3CH2COClB.C.Br2,CH3COOHOD.N(C2H5)2二.命名下列各化合物或写出结构式(每题1分,共10分)5BrClCHOHOH1.CH2OH2.HCl3....